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Q1. Which of these molecules best corresponds to the IR spectrum below?
A
B
C
D
E
Ans is D
Q2. Which of the following compounds will give a molecular ion having m/z = an odd number?
A
CH
3
CH
2
OH
B
CH
2
BrCl
C
CH
3
CO
2
H
D
CH
2
CH
2
NH
2
E
(CH
3
)
2
NCH
2
C≡N
Ans is D
Q3. What class of compounds is most likely to give a fragment ion at m/z = M-18?
A
alkenes
B
cycloalkanes
C
alcohols
D
alkyl iodides
E
benzene derivatives
Ans is D
Q4. Which of the following compounds is most likely to have its base peak at m/z = 43?
A
CH
3
(CH
2
)
4
CH
3
B
(CH
3
)
3
CCH
2
CH
3
C
cyclohexane
D
(CH
3
)
2
CHCH(CH
3
)
2
Ans is D
Q5. Which of the following statements regarding IR spectroscopy is correct?
A
IR radiation is higher in energy than UV radiation
B
IR spectra records the scattering of the radiation
C
IR spectra gives information about the ƛ max of the molecule
D
IR radiation is higher in wavelength than UV radiation
Ans is D
Q6. What is the condition for a molecule to be Microwave active?
A
Change in dipole movement
B
Change in polarisability
C
Permanent dipole movement
D
Isotopic labelling
Ans is C
Q7. Identify the correct statement.
A
NMR signals towards the left of the spectrum correspond to low chemical shift values.
B
NMR signals towards the right of the spectrum correspond to high chemical shift values
C
Chemical shift values are larger when shielding effects are greater
D
Chemical shift values are larger when deshielding effects are greater
Ans is D
Q8. The absorption intensity on an absorption spectrum tells us:
A
energy associated with a particular excitation.
B
the ease of transition.
C
the concentration of the absorbing part of the molecule.
D
both the ease of transition and the concentration of the absorbing part of the molecule.
Ans is C
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